2,6-Di-tert-butyl-4-(dimethyl­amino­meth­yl)phenol

نویسندگان

  • Tao Zeng
  • Yu-Ping Hou
چکیده

The title compound, C(17)H(29)NO, is an important hindered phenol derivative. The asymmetric unit contains two mol-ecules. Molecules inter-act through O-H⋯N hydrogen bonds to form a tetramer arranged around a twofold rotation axis.

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منابع مشابه

2,6-Di-tert-butyl-4-[(N-methyl­anilino)meth­yl]phenol

The title compound, C(22)H(31)NO, has been synthesized from 4-bromo-methyl-2,6-di-tert-butyl-phenol and N-methyl-aniline. There are two independent mol-ecules in the asymmetric unit. The aniline ring in each of the independent mol-ecules was found to be disordered, with site occupation factors 0.621 (10)/0.379 (10) and 0.605 (10)/0.395 (10).

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2,6-Di-tert-butyl-4-(methoxy­meth­yl)phenol

The title compound, C(16)H(26)O(2), was easily obtained in high yield when 4-bromo-methyl-2,6-di-tert-butyl-phenol was reacted with methanol. There are two independent mol-ecules in the asymmetric unit. The meth-oxy group in each of the independent mol-ecules was found to be disordered, with site-occupation factors of 0.8728 (18)/0.1272 (18) and 0.8781 (17)/0.1219 (17).

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Dimethyl 2-butyl-2-(3,5-di-tert-butyl-4-hydroxy­benz­yl)malonate

The title compound, C(25)H(38)O(5), was formed by the reaction of dimethyl 2-butyl-malonate and 2,6-di-tert-butyl-4-[(dimethyl-amino)meth-yl]phenol. In the crystal structure, mol-ecules are linked by inter-molecular O-H⋯O hydrogen bonds into chains along [010].

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4-tert-Butyl­pyridinium chloride–4,4′-(propane-2,2-di­yl)bis­(2,6-di­methyl­phenol)–toluene (2/2/1)

In the title solvated salt, C9H14N(+)·Cl(-)·C19H24O2·0.5C7H7, two mol-ecules of 4,4'-(propane-2,2-di-yl)bis-(2,6-di-methyl-phenol) are linked via O-H⋯Cl hydrogen bonds to two chloride ions, each of which is also engaged in N-H⋯Cl hydrogen bonding to a 4-tert-butyl-pyridinium cation, giving a cyclic hydrogen-bonded entity centred at 1/2, 1/2, 1/2. The toluene solvent mol-ecule resides in the lat...

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Synthesis of Liquid Antioxidant DTBNP Catalyzed by Composite Super Acid

2,6-Di-tert-butyl-4-nonylphenol(DTBNP) was synthesized from 4-n-nonyl phenol and isobutylene, etc. using self-made composite super acid as catalyst. The appropriate technology conditions are as follows: reaction temperature is 60-80 , reaction time is 4h, n 4-n-nonyl phenol : n Isobutylene = 1: 2 and the amount of catalysts is 0.019% of the quantity of 4-n-nonyl phenol reactant, the yield can r...

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عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2007